Search results for "Palladium nanowire"

showing 2 items of 2 documents

A nanostructured sensor of hydrogen peroxide

2017

Abstract A nanostructured electrochemical sensor of hydrogen peroxide was fabricated growing self-standing Pd nanowires (Pd NWs) into polycarbonate (PC) membranes through a simple metal galvanic deposition. Conditions of deposition were adjusted in order to attain 2–5 μm long Pd wires. Characterization of Pd-NWs was performed by scanning electrode microscopy, energy-dispersive X-ray spectroscopy and X-ray diffraction. Properties of the nanostructured sensor were studied by cyclic voltammetry and chronoamperometry in phosphate buffer—ethanol solution. Addition of pure ethanol to the test solution was essential in order to increase wettability of the nanostructures. Sensing features were comp…

Materials scienceAnalytical chemistryNanowirePalladium nanowireSurfaces Coatings and FilmNanoparticleCondensed Matter Physic02 engineering and technology010402 general chemistry01 natural scienceschemistry.chemical_compoundSpecific surface areaMaterials ChemistryElectrical and Electronic EngineeringHydrogen peroxideInstrumentationMaterials Chemistry2506 Metals and AlloyElectronic Optical and Magnetic MaterialMetals and AlloysChronoamperometryDisplacement depositionHydrogen peroxide021001 nanoscience & nanotechnologyCondensed Matter Physics0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsElectrochemical gas sensorTemplate synthesiSettore ING-IND/23 - Chimica Fisica ApplicataElectrochemical sensorchemistryChemical engineeringElectrodeNon-enzymatic sensor2506Cyclic voltammetry0210 nano-technologySensors and Actuators B: Chemical
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Synthesis of self-standing Pd nanowires via galvanic displacement deposition

2009

This work shows that it is possible to obtain self-standing Pd nanowires into anodic alumina membranes by a simple metal displacement deposition. By using a proper arrangement, specifically designed in order to optimize the process, polycrystalline Pd nanowires were deposited from a solution containing Pd(NH3)4(NO3)2 as precursor. Morphological analysis showed the formation of perfectly aligned nanowires with a uniform diameter throughout the entire length. This last parameter was controlled by both the deposition time and the ratio between the anodic area (active metal) and the cathodic area (pore bottom). Keywords: Displacement deposition, Template synthesis, Palladium nanowires, Alumina …

Materials scienceNanowireNanotechnologyAnodeCathodic protectionlcsh:ChemistryMembraneSettore ING-IND/23 - Chimica Fisica ApplicataChemical engineeringTransition metallcsh:Industrial electrochemistrylcsh:QD1-999ElectrochemistryGalvanic cellDeposition (phase transition)Displacement deposition Template synthesis Palladium nanowires Alumina membranesCrystallitelcsh:TP250-261Electrochemistry Communications
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